Metal and ligand-based reductions have been modeled in octahedral ruthenium complexes revealing metal–ligand interactions as the profound driving force for the redox-active behaviour of orthoquinoid-type ligands. Through an extensive investigation of redox-active ligands we revealed the most critical factors that facilitate or suppress redox-activity of ligands in metal complexes, from which basic rules for designing non-innocent/redox-active ligands can be put forward. These rules also allow rational redox-leveling, i.e.

The moderation of redox potentials of ligand-centred electron transfer processes, potentially leading to catalysts with low overpotential in multielectron activation processes. • For reproduction of material from NJC: [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC. • For reproduction of material from PCCP: [Original citation] - Published by the PCCP Owner Societies. • For reproduction of material from PPS: [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.

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• For reproduction of material from all other RSC journals: [Original citation] - Published by The Royal Society of Chemistry. Information about reproducing material from RSC articles with different licences is available on our.

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Install and run game. While the game is running, press Alt+Ctrl+Del to open up the task manager. Go to the Processes tab, find the name of the game (here is Dynabite.exe), end it.

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